Aqueous corrosion of phosphide minerals from iron meteorites: a highly reactive source of prebiotic phosphorus on the surface of the early Earth

We present the results of an experimental study of aqueous corrosion of Fe-phosphide under conditions relevant to the early Earth. The results strongly suggest that iron meteorites were an important source of reactive phosphorus (P), a requirement for the formation of P-based life. We further demonstrate that iron meteorites were an abundant source of phosphide minerals early in Earth history. Phosphide corrosion was studied in five different solutions: deionized water, deionized water buffered with sodium bicarbonate, deionized water with dissolved magnesium and calcium chlorides, deionized water containing ethanol and acetic acid, and deionized water containing the chlorides, ethanol, and acetic acid. Experiments were performed in the presence of both air and pure Ar gas to evaluate the effect of atmospheric chemistry. Phosphide corrosion in deionized water results in a metastable mixture of mixed-valence, P-bearing ions including pyrophosphate and triphosphate, key components for metabolism in modern life. In a pH-buffered solution of NaHCO(3), the condensed and reduced species diphosphonate is an abundant corrosion product. Corrosion in ethanol- and acetic acid-containing solutions yields additional P-bearing organic molecules, including acetyl phosphonate and a cyclic triphosphorus molecule. Phosphonate is a major corrosion product of all experiments and is the only P-bearing molecule that persists in solutions with high concentrations of magnesium and calcium chlorides, which suggests that phosphonate may have been a primitive oceanic source of P. The stability and reactivity of phosphonate and hypophosphite in solution were investigated to elucidate reaction mechanisms and the role of mineral catalysts on P-solution chemistry. Phosphonate oxidation is rapid in the presence of Fe metal but negligible in the presence of magnetite and in the control sample. The rate of hypophosphite oxidation is independent of reaction substrate.     

OSIRIS-REx low-velocity particles during outbound cruise

We analyzed high-angular rate streaks first recorded by OSIRIS-REx’s MapCam during a 2017 search for Earth Trojan asteroids. We interpret them as water-ice particles that translated across the imager’s field of view, originating from the spacecraft itself. Their translation velocities approximated 0.1–1?m/s based on reasonable conclusions about their range. Pursuing several lines of investigation to seek a coherent hypothesis, we conclude that the episodic releases of the water ice particles are associated with spacecraft attitudes that resulted in solar illumination of previously shadowed regions. This correlation suggests that the OSIRIS-REx spacecraft itself possesses micro-climatic zones consisting of hot regions and cold traps that may temporarily potentially pass volatiles back and forth before losing most of them.     

OSIRIS-REx: Sample Return from Asteroid (101955) Bennu

In May of 2011, NASA selected the Origins, Spectral Interpretation, Resource Identification, and Security–Regolith Explorer (OSIRIS-REx) asteroid sample return mission as the third mission in the New Frontiers program. The other two New Frontiers missions are New Horizons, which explored Pluto during a flyby in July 2015 and is on its way for a flyby of Kuiper Belt object 2014 MU69 on January 1, 2019, and Juno, an orbiting mission that is studying the origin, evolution, and internal structure of Jupiter. The spacecraft departed for near-Earth asteroid (101955) Bennu aboard an United Launch Alliance Atlas V 411 evolved expendable launch vehicle at 7:05 p.m. EDT on September 8, 2016, on a seven-year journey to return samples from Bennu. The spacecraft is on an outbound-cruise trajectory that will result in a rendezvous with Bennu in November 2018. The science instruments on the spacecraft will survey Bennu to measure its physical, geological, and chemical properties, and the team will use these data to select a site on the surface to collect at least 60 g of asteroid regolith. The team will also analyze the remote-sensing data to perform a detailed study of the sample site for context, assess Bennu’s resource potential, refine estimates of its impact probability with Earth, and provide ground-truth data for the extensive astronomical data set collected on this asteroid. The spacecraft will leave Bennu in 2021 and return the sample to the Utah Test and Training Range (UTTR) on September 24, 2023.

     

Regolith X-Ray Imaging Spectrometer (REXIS) Aboard the OSIRIS-REx Asteroid Sample Return Mission

The Regolith X-ray Imaging Spectrometer (REXIS) is the student collaboration experiment proposed and built by an MIT-Harvard team, launched aboard NASA’s OSIRIS-REx asteroid sample return mission. REXIS complements the scientific investigations of other OSIRIS-REx instruments by determining the relative abundances of key elements present on the asteroid’s surface by measuring the X-ray fluorescence spectrum (stimulated by the natural solar X-ray flux) over the range of energies 0.5 to 7 keV. REXIS consists of two components: a main imaging spectrometer with a coded aperture mask and a separate solar X-ray monitor to account for the Sun’s variability. In addition to element abundance ratios (relative to Si) pinpointing the asteroid’s most likely meteorite association, REXIS also maps elemental abundance variability across the asteroid’s surface using the asteroid’s rotation as well as the spacecraft’s orbital motion. Image reconstruction at the highest resolution is facilitated by the coded aperture mask. Through this operation, REXIS will be the first application of X-ray coded aperture imaging to planetary surface mapping, making this student-built instrument a pathfinder toward future planetary exploration. To date, 60 students at the undergraduate and graduate levels have been involved with the REXIS project, with the hands-on experience translating to a dozen Master’s and Ph.D. theses and other student publications.     

The OSIRIS-REx Radio Science Experiment at Bennu

The OSIRIS-REx mission will conduct a Radio Science investigation of the asteroid Bennu with a primary goal of estimating the mass and gravity field of the asteroid. The spacecraft will conduct proximity operations around Bennu for over 1 year, during which time radiometric tracking data, optical landmark tracking images, and altimetry data will be obtained that can be used to make these estimates. Most significantly, the main Radio Science experiment will be a 9-day arc of quiescent operations in a 1-km nominally circular terminator orbit. The pristine data from this arc will allow the Radio Science team to determine the significant components of the gravity field up to the fourth spherical harmonic degree. The Radio Science team will also be responsible for estimating the surface accelerations, surface slopes, constraints on the internal density distribution of Bennu, the rotational state of Bennu to confirm YORP estimates, and the ephemeris of Bennu that incorporates a detailed model of the Yarkovsky effect.     

OSIRIS-REx Flight Dynamics and Navigation Design

OSIRIS-REx is the first NASA mission to return a sample of an asteroid to Earth. Navigation and flight dynamics for the mission to acquire and return a sample of asteroid 101955 Bennu establish many firsts for space exploration. These include relatively small orbital maneuvers that are precise to ～1 mm/s, close-up operations in a captured orbit about an asteroid that is small in size and mass, and planning and orbit phasing to revisit the same spot on Bennu in similar lighting conditions. After preliminary surveys and close approach flyovers of Bennu, the sample site will be scientifically characterized and selected. A robotic shock-absorbing arm with an attached sample collection head mounted on the main spacecraft bus acquires the sample, requiring navigation to Bennu’s surface. A touch-and-go sample acquisition maneuver will result in the retrieval of at least 60 grams of regolith, and up to several kilograms. The flight activity concludes with a return cruise to Earth and delivery of the sample return capsule (SRC) for landing and sample recovery at the Utah Test and Training Range (UTTR).     

The OSIRIS-REx Thermal Emission Spectrometer (OTES) Instrument

The OSIRIS-REx Thermal Emission Spectrometer (OTES) will provide remote measurements of mineralogy and thermophysical properties of Bennu to map its surface, help select the OSIRIS-REx sampling site, and investigate the Yarkovsky effect. OTES is a Fourier Transform spectrometer covering the spectral range 5.71–100 μm (\(1750\mbox{--}100~\mbox{cm}^{-1}\)) with a spectral sample interval of \(8.66~\mbox{cm}^{-1}\) and a 6.5-mrad field of view. The OTES telescope is a 15.2-cm diameter Cassegrain telescope that feeds a flat-plate Michelson moving mirror mounted on a linear voice-coil motor assembly. A single uncooled deuterated l-alanine doped triglycine sulfate (DLATGS) pyroelectric detector is used to sample the interferogram every two seconds. Redundant ～0.855 μm laser diodes are used in a metrology interferometer to provide precise moving mirror control and IR sampling at 772 Hz. The beamsplitter is a 38-mm diameter, 1-mm thick chemical vapor deposited diamond with an antireflection microstructure to minimize surface reflection. An internal calibration cone blackbody target provides radiometric calibration. The radiometric precision in a single spectrum is \(\leq2.2 \times 10^{-8}~\mbox{W}\,\mbox{cm}^{-2}\,\mbox{sr} ^{-1}/\mbox{cm}^{-1}\) between 300 and \(1350~\mbox{cm}^{-1}\). The absolute integrated radiance error is \(<1\%\) for scene temperatures ranging from 150 to 380 K. The overall OTES envelope size is \(37.5 \times 28.9 \times 52.2~\mbox{cm}\), and the mass is 6.27 kg. The power consumption is 10.8 W average. OTES was developed by Arizona State University with Moog Broad Reach developing the electronics. OTES was integrated, tested, and radiometrically calibrated on the Arizona State University campus in Tempe, AZ.     

The OSIRIS-REx Laser Altimeter (OLA) Investigation and Instrument

Space Science Reviews - The Canadian Space Agency (CSA) has contributed to the Origins Spectral Interpretation Resource Identification Security-Regolith Explorer (OSIRIS-REx) spacecraft the...     

The OSIRIS-REx Spacecraft and the Touch-and-Go Sample Acquisition Mechanism (TAGSAM)

The Origins, Spectral-Interpretation, Resource-Identification, Security and Regolith-Explorer (OSIRIS-REx) spacecraft supports all aspects of the mission science objectives, from extensive remote sensing at the asteroid Bennu, to sample collection and return to Earth. In general, the success of planetary missions requires the collection, return, and analysis of data, which in turn depends on the successful operation of instruments and the host spacecraft. In the case of OSIRIS-REx, a sample-return mission, the spacecraft must also support the acquisition, safe stowage, and return of the sample. The target asteroid is Bennu, a B-class near-Earth asteroid roughly 500 m diameter. The Lockheed Martin-designed and developed OSIRIS-REx spacecraft draws significant heritage from previous missions and features the Touch-and-Go-Sample-Acquisition-Mechanism, or TAGSAM, to collect sample from the surface of Bennu. Lockheed Martin developed TAGSAM as a novel, simple way to collect samples on planetary bodies. During short contact with the asteroid surface, TAGSAM releases curation-grade nitrogen gas, mobilizing the surface regolith into a collection chamber. The contact surface of TAGSAM includes “contact pads”, which are present to collect surface grains that have been subject to space weathering. Extensive 1-g laboratory testing, “reduced-gravity” testing (via parabolic flights on an airplane), and analysis demonstrate that TAGSAM will collect asteroid material in nominal conditions, and a variety of off-nominal conditions, such as the presence of large obstacles under the TAGSAM sampling head, or failure in the sampling gas firing. TAGSAM, and the spacecraft support of the instruments, are central to the success of the mission.